The aim of the following exposition is a definition of physical terms essential for an informed discussion of which of these properties have a solid basis in physics, and which of these are gross misconceptions or exaggerations that shouldn’t be taken seriously. Such a discussion is begun in another Insight Article “Misconceptions about Virtual Particles“. A further Insight Article, ”Vacuum Fluctuations in Experimental Practice”, shows at the example of a recent article in the scientific literature how some authors claim the observation of vacuum fluctuations, justified only by superficial, invalid reasoning.
In the following, I give precise definitions of many terms, telling what they really mean as part of the technical language used in quantum field theory. They have meaning only in this precisely defined context, and are meaningless otherwise. For example, virtual particles have a technical meaning in a discussion of Feynman diagrams, but not in stories where they are claimed to pop in and out of existence. Similarly, vacuum fluctuations have a technical meaning in a discussion of certain vacuum expectation values, but not in stories where they are claimed to describe a sizzling vacuum, or to cause a physical effect.
Physical system. A physical system is characterized abstractly by the collection of observables that are meaningfully assignable to the system, the defining commutation relations specifying a Lie algebra, and its representation on a Hilbert space. The spectral analysis of this representation determines the possible values the observables can take. The most well-known example is an oscillator, whose observables are scalar position and momentum variables satisfying the canonical commutation rules and can take arbitrary real values.
Particle. Particles are particularly simple physical systems. Particles of subatomic size are described in physics by relativistic quantum field theory. Contrary to the naive view as tiny bullets, particles are described on this fundamental level as oscillations of the quantum fields, typically partially localized in a beam. The mass ##m## of a massive particle is proportional to the (angular) oscillation frequency ##\omega## in their rest frame, according to the formula ##\hbar\omega=E=mc^2##, where ##\hbar## is Planck’s constant, ##c## the speed of light, and ##E## the rest energy of the particle. Thus real mass is the relativistic analogue of real frequencies, corresponding to stable particles and stable oscillations, and complex mass is the relativistic analogue of complex frequencies, corresponding to decaying particles and decaying oscillations.
Elementary particle. Whether a particle is or is not elementary depends on the description level. As our knowledge about microscopic physics increases, objects once considered as elementary were found to have substructure that can be modeled on a more detailed level. Thus atoms, once thought of as elementary are today described as consisting of nuclei and electrons; nuclei are described as consisting of protons and neutrons, and the latter are thought of consisting of quarks. Whether quarks have substructure is presently unknown.
A particle is considered to be elementary (on a given description level) if it is sufficient to describe it by an irreducible unitary representation of the Poincare group or its Lie algebra. This group is dictated in QFT by the symmetries of space-time at experimental microscopic scales. The 10 independent observables of this Lie algebra are the four components of a 4-vector ##p## describing momentum, three components of a 3-vector ##J## describing angular momentum, and three components of another 3-vector ##K## describing infinitesimal boosts.
For massive particles such as the electron, one can construct from these an additional 3-vector ##q## describing the particle position in an observer-dependent frame. For massless particles such as the photon, a sensible position vector does not exist.
States. A specific instance of the physical system is described by a state – either a pure state specified by a normalized state vector ##\psi## in the Hilbert space of the system, or a mixed state specified by a Hermitian positive semidefinite density operator ##\rho## of trace 1 acting on the Hilbert space; this also covers the pure case with ##\rho=\psi\psi^*##. The state specifies the probabilities with which the observables can be observed in appropriate experiments. Unless the state of a physical system is specified it is impossible to say anything at all about its observables, apart from the possible values they can take when realized through a state. Thus states are necessary to relate the formal properties to reality. Properties not expressible in terms of states have no observable meaning.
Observable particles. Relativistic quantum field theory (QFT) is the theory for predicting the results of collision experiments, the main source of information about subatomic particles. In relativistic QFT, observable – hence undisputably real – particles of mass ##m## are asymptotic objects, sufficiently far (in theory infinitely far) away that their interactions can be neglected. This is the content of the cluster decomposition principle, realized through the S-matrix, in which a time limit ##t\to\pm\infty## is performed. Negative infinite time corresponds to (typically two) ingoing particles in a collision experiment, positive infinite times to (typically two or more) outgoing particles, the collision products.
Observable particles are conventionally defined as being associated with poles of the S-matrix at energy ##E=mc^2## in the rest frame of the system (Peskin/Schroeder, An introduction to QFT, p.236). If the pole is at a real energy, the mass is real and the particle is a stable bound state; if the pole is at a complex energy (in the analytic continuation of the S-matrix to the second sheet), the mass is complex and the particle is unstable. At energies larger than the real part of the mass, the imaginary part determines its decay rate and hence its lifetime (Peskin/Schroeder, p.237); at smaller energies, the unstable particle cannot form for lack of energy, but the existence of the pole is revealed by a Breit-Wigner resonance in certain cross sections. From its position and width, one can estimate the mass and the lifetime of such a particle before it has ever been observed. Indeed, many particles listed in the tables by the Particle Data Group (PDG) are only known as resonances.
Stable and unstable particles. A stable particle can be created and annihilated, as there are associated creation and annihilation operators that add or remove particles to the state. According to the QFT formalism, these particles must be on-shell. This means that their momentum ##p## is related to the real rest mass mm by the relation ##p^2=m^2## (in units where ##c=1##).
More precisely, it means that the 4-dimensional Fourier transform of the time-dependent single-particle wave function associated with it has a support that satisfies the relation ##p^2=m^2##. There is no need for this wave function to be a plane wave, though these are taken as the natural unnormalized basis functions between the scattering matrix elements are taken.
An unstable particle is represented quantitatively by a so-called Gamov state, also called a Siegert state, in a complex deformation of the Hilbert space of a QFT obtained (e.g., thorough complex scaling) by analytic continuation of the formulas for stable particles. In this case, as ##m## is complex, the mass shell consists of all complex momentum vectors ##p## with ##p^2=m^2## and ##v=p/m## real, and states are composed exclusively of such momentum vectors. This is the representation in which one can take the limit of zero decay, in which the particle becomes stable (such as the neutron in the limit of negligible electromagnetic interaction), and hence the representation appropriate in the regime where the unstable particle can be observed (i.e., resolved in time). Note that particles that are unstable in the standard model of QFT may be stable in a submodel – for example, the neutron is an unstable particle, decaying through the weak force, but within QCD (which models only the strong force) it is a stable bound state of three quarks.
Resonances. A second representation of unstable particles in terms of normalizable states of real mass is given as the superposition of the scattering states of their decay products, involving all energies in the range of the Breit-Wigner resonance. In this standard Hilbert space representation, the unstable particle is never formed; so this is the representation appropriate in the regime where the unstable particle reveals itself only as a resonance. For example, the 2010 PDG description of the Z boson discusses both descriptions of the unstable ##Z## in quantitative detail (p.2: Breit-Wigner approach; p.4: S-matrix approach). For the ##\rho## meson, see, e.g., the slides by Hendrik van Hees.
Branching fractions. If an unstable particle can decay in several different ways, the branching fraction of each single decay (or group of decays) is the relative frequency of this decay (or group of decays) compared to all decays. It can be computed from the S-matrix elements of all individual processes.
Transition states. These are short-living (hence real) intermediate states in a chemical (or nuclear) reaction,or any other collision process, often visible as resonances. Their theory is a well-developed science in the case of chemical and nuclear reactions, and it applies in principle down to the smallest scales. See, e,g,, Hänggi, P., Talkner, P., & Borkovec, M. (1990). Reaction-rate theory: fifty years after Kramers. Reviews of modern physics, 62(2), 251.
Quasiparticles. The particles described by the S-matrix are the elementary excitations of the vacuum state. At finite temperature and in general relativity, the asymptotic particle concept in quantum field theory must be modified to take account of a nontrivial background. Typically, the background (which takes the place of the vacuum state) is modeled as a coherent state or a squeezed state, or their fermionic analogue. Quasiparticles are the elementary excitations of the background, treated as if it were a vacuum state; the background also deforms the mass shell, leading to a dispersion law different from ##p^2=m^2##. Moreover, the space-time symmetry is broken. Typical examples of quasiparticles are phonons in solid state physics and Cooper pairs in superconductivity. Quasiparticles are associated with states and creation and annihilation operators, hence are as real as ordinary particles.
On-shell and off-shell particles. The mass shell of a particle of (real or complex) mass ##m## is the 3-dimensional quadric ##p^2=m^2## in 4-dimensional momentum space. On-shell means that this equation holds, off-shell that this equation is violated. All observable particles are on-shell, though the mass shell is real only for stable particles. Therefore, off-shell particles (also called virtual particles; see below) are necessarily unobservable.
Feynman diagrams. Feynman diagrams describe how the terms in a series expansion of the S-matrix elements arise in a perturbative treatment of the interactions as linear combinations of multiple integrals. Each such multiple integral is a product of vertex contributions and propagators, and each propagator depends on a 4-momentum vector that is integrated over. In additon, there is a dependence on the momenta of the ingoing (prepared) and outgoing (in principle detectable) particles.
The structure of each such integral can be concisely represented by a Feynman diagram. This is done by associating with each vertex a node of the diagram and with each momentum a line; for ingoing momenta an external line ending in a node, for outgoing momenta an external line starting in a node, and for propagator momenta an internal line between two nodes. The detailed correrspondence is given by the so-called Feynman rules found in every QFT book.
The resulting diagrams can be given a very vivid but superficial interpretation as the worldlines of particles that undergo a metamorphosis (creation, deflection, or decay) at the vertices. In this interpretation, the in- and outgoing lines are the worldlines of the prepared and detected particles, respectively, and the others are dubbed virtual particles, not being real but required by this interpretation. This interpretation is related to – and indeed historically originated with – Feynman’s 1945 intuition that all particles take all possible paths with a probability amplitute given by the path integral density. Unfortunately, such a view is related to the formal, unrenormalized path integral only. But on the unrenormalized level all contributions of diagrams containing loops are infinite, defying a probability interpretation.
External lines and off-shell particles. As a consequence of the description of S-matrix elements, the external lines usually correspond to on-shell particles. and then describe real particles before and after a collision or decay. However, there is the custom of using (generalized) Feynman diagrams also in certain cases where one or more out-particles are off-shell (typically denoted by a *). An example (see Figure 2 in http://arxiv.org/abs/hep-ph/9807536) is the Higgs decay ##H\to WW^*## in which one of the ##W## produced is off-shell, hence not a real particle but an unobservable label. Such a Feynman diagram is short-hand for a family of Feynman diagrams obtained by attaching to each off-shell particle another vertex and its admissble interaction partners, in case of the ##W^*## two leptons. Thus the single Feynman diagram visualizing the decay ##H\to WW^*## stands in fact for ##H\to WX##, where ##X## are two external lepton lines attached to a vertex that turns ##W^*## into an internal line, as it should be for off-shell particles. The branching fractions for decays involving off-shell particles must be interpreted in the same way. For example, the branching factor for the decay ##H\to WW^*## is defined as the inclusive branching factor for all ##H\to WX##, where ##X## are two observable leptons consistent with the standard model interactions.
Virtual particles. Virtual particles are defined as (intuitive imagery for) internal lines in a Feynman diagram (Peskin/Schroeder, p.5, or Zeidler, QFT I Basics in mathematics and physics, p.844). They are frequently used by professionals to illustrate processes in quantum field theory, and as a very useful shorthand language for complicated multivariate integrals over internal (real, but off-shell) momenta. According to the definition in terms of Feynman diagrams, a virtual particle has a real mass and specific values of 4-momentum, spin, and charges, characterizing the form and variables in its defining propagator. As the 4-momentum is integrated over all of ##R^4##, there is no mass shell constraint, hence virtual particles are off-shell. The word virtual is an antonym to real – unlike the general readership of popular literature on particle physics, the creators of the terminology were well aware that virtual particles are not real in any observable sense. See the final paragraph of this article.
Informally, virtual particles are primarily viewed as transmitting the fundamental forces in quantum field theory.The electromagnetic force is transmitted by virtual photons. The weak force is transmitted by virtual Zs and Ws. The strong force is transmitted by virtual gluons. The physics underlying this figurative speech is in the Feynman diagrams, primarily in the simplest tree diagrams that encode the low order perturbative contributions of interactions to the classical limit of scattering experiments. (Thus the tree diagrams are really a manifestation of classical perturbative field theory, not of quantum fields. Quantum corrections involve at least one loop.)
Virtual states. In nonrelativistic scattering theory, one also meets the concept of virtual states, denoting states of real particles on the second sheet of the analytic continuation, having a well-defined but purely imaginary energy, defined as a pole of the S-matrix. See, e.g., Thirring, A course in Mathematical Physics, Vol 3, (3.6.11).
The term virtual state is used with a different meaning in virtual state spectroscopy and denotes there an unstable energy level above the dissociation threshold, with small imaginary parts. This is equivalent with the concept of a resonance discussed above.
Virtual states have nothing to do with virtual particles, which have real energies but no associated states, though sometimes the name ”virtual state” is associated to the latter.
Misconceptions about virtual particles. That virtual particles transmit the fundamental forces proves the ”existence” of virtual particles in the eyes of their afficionados. But since they lack states (multiparticle states are always composed of on-shell particles only), they lack reality in any meaningful sense. States involving virtual particles cannot be created for lack of corresponding creation operators in the theory. Thus they cannot cause anything or interact with anything. In short, virtual particles are ”virtual” particles only, as their name says.
For a fuller discussion of the many widespread misconceptions surrounding the concept of virtual particles see Chapter A8: ”Virtual particles and vacuum fluctuations” of my theoretical physics FAQ. Se also the discussions on this forum here, here, here, and here. Finally, see also this thread from Physics Stack Exchange, a predecessor of the above text, and the discussions here and there relating to that thread.
I’ll close with a clarification of the scientific content of some often misunderstood concepts related to the vacuum.
Vacuum fluctuations. This is the term associated with the formal fact that the distribution of a smeared electromagnetic field operator in the vacuum state of a free quantum field theory is a Gaussian. (See p. 119 in the book Quantum Field Theory by Itzykson and Zuber 1980.)
According to the Born rule, the distribution of a quantum observable gives the probabilities for measuring values for the observable in independent, identical preparations of the system in identical states. Thus the presence of a Gaussian distribution means that the value of the electromagnetic field in the vacuum state is not determined with arbitrary precision but has an inherent uncertainty.
No temporal or spatial implications can be deduced. (The distribution itself is independent of time and space.) Thus it is misleading to interpret vacuum fluctuations as fluctuations in the common sense of the word, which is the traditional name for random changes in space and time. The vacuum is isotropic (i.e., uniform) in space and time and does not change at all. The particle number does not fluctuate in the vacuum state; it is exactly zero since the vacuum state is an eigenstate of the number operator and its local projections in space-time, with eigenvalue zero. Thus there is no time or place where the vacuum can contain a particle. In particular, in a vacuum particles are nowhere created or destroyed, not even in the tiniest time interval.
Vacuum expectation values (VEVs) are the expectation values of fields or expressions in fields, typically (either Wightman or time-ordered) field correlations. The more technical name for the latter is ##N##-point functions. They express information about the fields that can be compared with experiment. Indeed, they represent the only information that can be extracted from a quantum field theory. However, vacuum expectation values appear in any perturbative computation of anything in quantum field theory, hence doesn’t say anything nontrivial. One can measure spectral shifts whose size is perturbatively given by VEVs, or fluctuating signals whose variance is explained by VEVs; but claiming that therefore one has measured vacuum fluctuations is meaningless.
Vacuum diagrams (or vacuum bubbles) are Feynman diagrams without external lines. They do not appear in any calculation of S-matrix elements, which connect the formalism of perturbative quantum field theory to quantities measurable in collision experiments. (Mathematically this happens because the effective action is the logarithm of the series of all Feynman terms, and only the connected diagrams contribute to the series for the logarithm.) As a consequence, vacuum diagrams have no physical interpretation; in particular, they do not enter the formulas for vacuum expectation values (and hence vacuum fluctuations). The name comes from the form in which these diagrams are conventionally drawn, and doesn’t point to anything bubbling in the vacuum.
Vacuum polarization is the name for the radiation corrections to the photon self-energy. If computed in perturbation theory, it is given by the sum of all Feynman diagrams with two external photon lines. It is a physical effect caused by the interaction with the electron field, not by the virtual particles in the diagrams, which are pure mnemonic for the integrals used for the computation and play no causal role.