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zeroth law of thermodynamics
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Definition/Summary
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If body A is in thermal equilibrium with body B, and body C is in thermal equilibrium with body B, then body A is in thermal equilibrium with body C.
The concept which arises from the zeroth law is that of temperature. |
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Recent forum threads on zeroth law of thermodynamics
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Breakdown
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Physics
> Statistical & Thermal
>> Thermodynamic Laws
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Extended explanation
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Formal Argument in Favour of Temperature
Consider three systems of gas A, B and C. If A and B are in thermal equilibrium then there is a definite relationship between PA VA & PB VB. We can write this relationship as:
[tex] F_1 (P_A,V_A,P_B,V_B) = 0[/tex]
Likewise for gases B and C:
[tex] F_2 (P_B, V_B,P_C,V_C) = 0[/tex]
Rearranging the equations above:
[tex] P_B = f_1(P_A,V_A,V_B) = f_2(P_C,V_C,V_B)[/tex]
From the zeroth law we have:
[tex]F_3(P_A, V_A,P_C,V_C) = 0[/tex]
So:
[tex] P_A=f_3(V_A,P_C,V_C) [/tex]
Thus VB does not need to appear and can be removed from previous functions. So for systems in thermal equilibrium, there is a function of their parameters that is common to both systems.
i.e. [tex]f(P,V) = \theta[/tex]
where [itex]\theta[/itex] is empirical temperature and [itex]f(P,V)[/itex] is the equation of state.
So we can say that two objects in thermal equilibrium have the same temperature. |
Commentary
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Kurdt @ 06:26 AM Jun16-08
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Kurdt @ 08:42 AM May13-08
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Accio @ 06:33 AM May13-08
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